This image was generated by scanning X-ray microdiffraction (µSXRD) with submicron spatial resolution. Laue diffraction (a) from an unconstrained Sb2S3 single crystal (top) and laser fabricated RLS crystal Sb2S3 (bottom). Magnified images (b) of selected reflection extracted from Laue patterns (a, bottom) obtained for different points of the RLS crystal (c). Image: D. Savytskii, H. Jain, N. Tamura & V. Dierolf.
This image was generated by scanning X-ray microdiffraction (µSXRD) with submicron spatial resolution. Laue diffraction (a) from an unconstrained Sb2S3 single crystal (top) and laser fabricated RLS crystal Sb2S3 (bottom). Magnified images (b) of selected reflection extracted from Laue patterns (a, bottom) obtained for different points of the RLS crystal (c). Image: D. Savytskii, H. Jain, N. Tamura & V. Dierolf.

Scientists at Lehigh University, in collaboration with colleagues at the Lawrence Berkeley National Laboratory, have fabricated a new class of crystalline solid known as a rotating lattice single (RLS) crystal. To do this, they used a laser-heating technique that induces atoms to organize into a rotating lattice without affecting the macroscopic shape of the solid.

By controlling the rotation of the crystalline lattice, the researchers say they will be able to make new types of synthetic single crystals, as well as ‘bio-inspired’ materials that mimic the structure and superior electronic and optical properties of special biominerals.

The group reports its findings in a paper in Scientific Reports; the paper's lead author is Dmytro Savytskii, a research scientist in the department of materials science and engineering at Lehigh. The other authors are: Volkmar Dierolf, distinguished professor and chair of the department of physics at Lehigh; Himanshu Jain, professor of materials science and engineering at Lehigh; and Nobumichi Tamura at the Lawrence Berkeley National Laboratory.

The development of the RLS crystals follows a discovery reported in March in Scientific Reports in which the Lehigh group demonstrated for the first time that a single crystal could be grown from glass without melting the glass.

In a typical crystalline solid, atoms are arranged in a lattice – a regularly repeating, or periodic, three-dimensional (3D) structure. When viewed from any angle – left to right, up and down, front to back – a crystal-specific periodicity becomes evident. Glass, by contrast, is an amorphous material with a disordered atomic structure.

Because they have no grain boundaries between interconnecting crystals, single-crystal materials often possess exceptional mechanical, optical and electrical properties. Single crystals give diamonds their brilliance and jet turbine blades their resistance to mechanical forces. And the single crystal of silicon in a silicon chip gives it superior conducting properties that form the basis for microelectronics.

The periodicity, or repeating pattern, in a rotating lattice single crystal, said Jain and Dierolf, differs from the periodicity in a typical single crystal. "We have found that when we grow a crystal out of glass," said Jain, "the periodicity does not result the same way. In one direction, it looks perfect, but if you turn the lattice and look at it from a different angle, you see that the whole structure is rotating."

"In a typical single-crystal material," said Dierolf, "once I figure out how the pattern repeats, then, if I know the precise location of one atom, I can predict the precise location of every atom. This is possible only because single crystals possess a long-range order.

"When we grow an RLS crystal out of glass, however, we have found that the periodicity does not result the same way. To predict the location of every atom, I have to know not just the precise location of a particular atom but the rotation angle of the lattice as well. Thus, we have to slightly modify the textbook definition of single crystals."

The rotation, said Jain, occurs at the atomic scale and does not affect the shape of the glass material. "Only the string of atoms bends, not the entire material. We can see the bending of the crystal lattice with x-ray diffraction."

To achieve this rotation, the researchers heated a very small portion of the surface of a solid glass material made from the mineral stibnite (Sb2S3) with a laser, which causes the atoms to become more flexible.

"The atoms want to arrange in a straight line but the surrounding glass does not allow this," said Jain. "Instead, the glass, being completely solid, forces the configuration of the atoms to bend. The atoms move and try to organize in a crystalline lattice, ideally in a perfect single crystal, but they cannot because the glass prevents the perfect crystal from forming and forces the atoms to arrange in a rotational lattice. The beauty is that the rotation occurs smoothly on the micrometer scale."

"Our laser imposes a degree of asymmetry on the growth of the crystal," he adds. "We control the asymmetry of the heating source to impose this rotational pattern on the atoms."

The group's ability to control the amount of heating is critical to the formation of the rotating lattice, said Jain. "The key to the creation of the rotating atomic lattice is that it occurs without melting the glass. Melting allows too much freedom of atomic movement, which makes it impossible to control the organization of the lattice."

"Our subtle way of heating the glass overcomes this," he explains. "We heat only the surface of the glass, not inside. This is very precise, very localized heating. It causes only a limited movement of the atoms, and it allows us to control how the atomic lattice will bend."

Rotating lattices have been observed in certain biominerals in the ocean, said Jain and Dierolf, and it may also occur on a very small scale in some natural minerals, such as spherulites. "But no one had previously made this on a larger scale in a controlled way, which we have accomplished with the asymmetrical imposition of a laser to cause the rotating lattice," said Jain.

"Scientists were not able to understand this phenomenon before because they could not observe it on a large enough scale. We are the first group to induce this to happen on an effectively unlimited dimension with a laser."

Jain and Dierolf and their group are now planning further studies to improve their ability to manipulate the ordering of the atoms. The researchers performed the laser heating of the glass at Lehigh, and then characterized the glass with micro x-ray diffraction on a synchrotron at the Lawrence Berkeley National Laboratory. They plan to perform further characterization at Berkeley and with electron microscopy at Lehigh.

"This is a novel way of making single crystals," said Dierolf. "It opens a new field by creating a material with unique, novel properties."

This story is adapted from material from Lehigh University, with editorial changes made by Materials Today. The views expressed in this article do not necessarily represent those of Elsevier. Link to original source.