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Carbon nanotube in different shapes

27 June 2009
Mei Zhang and Jian Li

Carbon nanotubes (CNTs) have been well studied theoretically and experimentally. Perfect CNTs have a crystalline structure formed by hexagonal network; defects cause the tubule to curve. CNTs with different tubule morphologies have their own special properties and potential applications. So far, many different shapes, such as straight, waved, coiled, and branched, are predicted, observed, and target synthesized. This article reviews CNTs in different shapes formed during growth, their morphologies and their possible applications.

 

Carbon Nanotubes (CNTs) are cylindrical shells made, in concept, by rolling graphene sheets into a seamless cylinder. CNTs exist as either single-wall nanotubes (SWNTs) or multi-walled nanotubes (MWNTs). The SWNT consists of a single graphene sheet, which is a planar array of benzene molecules, involving only hexagonal rings with double and single carbon-carbon bonding. The choice of rolling axis relative to the hexagonal network of the graphene sheet and the radius of the closing cylinder allows for different types of SWNTs, which vary from insulating to conducting1. Figures 1a, 1b, and 1c show SWNTs of three different types2: armchair, zigzag, and chiral. The twist of the chiral nanotube is clearly evident in the lower Fig. 1c, a perspective view along the tube axis, and in Fig. 1d, a scanning probe microscope (SPM) picture of a chiral SWNT3. MWNTs comprise an array of such nanotubes that are concentrically nested. A transmission electron microscope (TEM) image of a nine-walled CNT is shown in Fig. 1e. CNTs with perfect crystalline structure are straight cylinders.

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Nanotechnology