Paul Voyles from the University of Wisconsin-Madison.For millennia, people have used molten sand and other ingredients to create glass and fashion beads, vessels, lenses and windows. These days, metallic glasses – made entirely of metal atoms – are being developed for biomedical applications such as extra-sharp surgical needles, stents, and artificial joints or implants because the glasses can be ultra-hard, extra-strong, very smooth and resistant to corrosion.
While a combination of trial and error and scientific research has helped refine glass-making processes over time, controlling the creation of metallic glasses at the atomic level remains an inexact endeavor informed largely by long experience and intuition.
"Our job," says Paul Voyles, professor in materials science and engineering at the University of Wisconsin-Madison, "is to build fundamental understanding by adding more data."
Voyles and collaborators in Madison and at Yale University have now made significant experimental strides in understanding how, when and where the constantly moving atoms in molten metal ‘lock’ into place as the material transitions from liquid to solid glass. They report their findings in a paper in Nature Communications.
This new knowledge can add much-needed experimental clarity to several competing theories about how that process, known as glass transition, occurs. It could also help reduce the time and costs associated with developing new metallic glass materials, and provide manufacturers greater insight into process design.
One major processing challenge with metallic glasses arises from the fact that as metals transition from molten liquid to solid, they tend to form orderly, regularly repeating atomic structures called crystals. In contrast, glass materials have a highly disordered atomic structure. And while making a high-performance metallic glass sounds as simple as preventing metal atoms from forming crystals as the metal cools, in reality it relies somewhat on the luck of the draw.
"The process that makes a glass and the process that makes a crystal compete with each other, and the one that wins – the one that happens at a faster rate – determines the final product," says Voyles, whose work is supported by the US National Science Foundation and the US Department of Energy.
In a liquid, all of the atoms are moving past each other at all times. As a molten metal cools, and begins its transition to a solid, its atoms slow down and eventually stop moving. It's a complicated atomic-level dance that scientists are still unraveling. Drawing on their expertise in electron microscopy and data analysis, Voyles and his collaborators have now measured how long it takes, on average, for an atom to gain or lose adjacent atoms as its environment fluctuates in the molten liquid.
"An atom is surrounded by a bunch of other atoms," Voyles explains. "At really high temperatures, they bounce around and every picosecond (one trillionth of a second), they have a new set of neighbors. As the temperature decreases, they stick with their neighbors longer and longer until they stick permanently."
At high temperatures, the atoms all move fast. Then, as the liquid cools, they move more slowly. The simplest way to picture this happening is for all of the atoms to slow down together, at the same rate, until they stop moving and the material becomes a solid glass.
"We have now demonstrated experimentally that is not what happens," says Voyles.
Rather, his team's experiments confirm that the time it takes for atoms to lock into place varies widely – by at least an order of magnitude – from place to place inside the same liquid.
"Some nanometer-sized regions get 'sticky' first and hold on to their neighbors for a very long time, whereas between the sticky bits are bits that are moving much more quickly," he says. "They continue to fluctuate 10 times faster than in the slow parts and then everything gets slower, but the sticky parts also get bigger until the sticky parts 'win' and the material becomes a solid."
Now, he and his collaborators are working to understand how the atomic arrangements differ between the slow and fast parts: "That's the next big missing piece of the puzzle."
According to Voyles, this advance provides valuable information about the fundamental process through which every glass material – from window glass to plastic bottles to pharmaceutical preparations and many others – transitions from liquid to solid.
"This is really basic science," he says. "But the ultimate potential impact for applications is if we really understand how this works at the atomic level, that gives us the opportunity to build in control that lets us make glasses out of what we want instead of only getting glasses when we get lucky."
This story is adapted from material from the University of Wisconsin-Madison, with editorial changes made by Materials Today. The views expressed in this article do not necessarily represent those of Elsevier. Link to original source.