Bubbles of distortion clearly spotted in perovskite solar cells

Polarons are fleeting distortions in a material's atomic lattice that form around a moving electron in a few trillionths of a second, then quickly disappear. As ephemeral as they are, they can affect a material's behavior, and may even be the reason that solar cells made with lead hybrid perovskites achieve such extraordinarily high efficiencies in the lab.

Now, scientists at the US Department of Energy (DOE)'s SLAC National Accelerator Laboratory and Stanford University have used the lab's X-ray laser to watch and directly measure the formation of polarons for the first time. They report their findings in a paper in Nature Materials.

"These materials have taken the field of solar energy research by storm because of their high efficiencies and low cost, but people still argue about why they work," said Aaron Lindenberg, an investigator with the Stanford Institute for Materials and Energy Sciences (SIMES) at SLAC and an associate professor at Stanford, who led the research.

"The idea that polarons may be involved has been around for a number of years. But our experiments are the first to directly observe the formation of these local distortions, including their size, shape and how they evolve."

Perovskites are crystalline materials named after the mineral perovskite, which has a similar atomic structure. Scientists started to incorporate perovskites into solar cells about a decade ago. Since then, the efficiency of these cells at converting sunlight to energy has steadily increased, despite the fact that the perovskite components have a lot of defects that should inhibit the flow of current.

These materials are famously complex and hard to understand, Lindenberg said. Scientists find them exciting because they are both efficient and easy to produce, raising the possibility that they could make solar cells cheaper than today's silicon cells. But they are also highly unstable, breaking down when exposed to air, and contain lead that has to be kept out of the environment.

Previous studies at SLAC have delved into the nature of perovskites with an 'electron camera' or with X-ray beams. Among other things, these studies revealed that light whirls atoms around in perovskites; they also measured the lifetimes of acoustic phonons – sound waves ­- that carry heat through the materials.

For this study, Lindenberg's team used SLAC's Linac Coherent Light Source (LCLS), a powerful X-ray free-electron laser that can image materials in near-atomic detail and capture atomic motions occurring over millionths of a billionth of a second. They investigated single crystals of hybrid perovskite, synthesized by Hemamala Karunadasa's group at Stanford, by hitting the crystals with light from an optical laser and then using the X-ray laser to observe how they responded over the course of tens of trillionths of a second.

"When you put a charge into a material by hitting it with light, like what happens in a solar cell, electrons are liberated, and those free electrons start to move around the material," explained Burak Guzelturk, a scientist at DOE's Argonne National Laboratory who was a postdoctoral researcher at Stanford at the time of the experiments.

"Soon they are surrounded and engulfed by a sort of bubble of local distortion – the polaron – that travels along with them. Some people have argued that this 'bubble' protects electrons from scattering off defects in the material, and helps explain why they travel so efficiently to the solar cell's contact to flow out as electricity."

The hybrid perovskite lattice structure is flexible and soft – like "a strange combination of a solid and a liquid at the same time", as Lindenberg puts it – and this is what allows polarons to form and grow.

The scientists' observations revealed that polaronic distortions start very small – on the scale of a few angstroms, about the spacing between atoms in a solid – and rapidly expand outward in all directions to a diameter of around five billionths of a meter, which is about a 50-fold increase. This nudges about 10 layers of atoms slightly outward within a roughly spherical area over the course of tens of picoseconds, or trillionths of a second.

"This distortion is actually quite large, something we had not known before," Lindenberg said. "That's something totally unexpected.

"While this experiment shows as directly as possible that these objects really do exist, it doesn't show how they contribute to the efficiency of a solar cell. There's still further work to be done to understand how these processes affect the properties of these materials."

This story is adapted from material from the SLAC National Accelerator Laboratory, with editorial changes made by Materials Today. The views expressed in this article do not necessarily represent those of Elsevier. Link to original source.