This figure shows the transition process of carriers between different localization states with increasing temperatures. Image: Yangfeng Li.Indium gallium nitride (InGaN) achieves a better luminescence efficiency in light-emitting diodes (LEDs) than many of the other materials used to create blue and green LEDs. But a big challenge of working with InGaN is its dislocation density defects, which make understanding its emission properties quite difficult.
In a paper in the Journal of Applied Physics, researchers in China now report an InGaN LED structure with high luminescence efficiency and what is believed to be the first direct observation of transition carriers between different localization states within InGaN. The localization states were confirmed by temperature-dependent photoluminescence and excitation power-dependent photoluminescence.
Localization states theory is commonly used to explain how InGaN materials can have a high luminescence efficiency despite containing a large number of dislocations. Localization states are the energy minima states believed to exist within the InGaN quantum well region (discrete energy values), but a direct observation of localization states had been elusive until now.
"Based primarily on indium content fluctuations, we explored the 'energy minima' that remain within the InGaN quantum well region," said Yangfeng Li, the paper's lead author and now a postdoctoral fellow at the Hong Kong University of Science and Technology. "Such energy minima will capture the charge carriers – electrons and holes – and prevent them from being captured by defects (dislocations). This means that the emission efficiency is less affected by the large number of defects."
The group's direct observation of localization states is an important discovery for the future of LEDs, because it verifies their existence, which was a long-standing open scientific question.
"Segregation of indium may be one of the reasons causing localization states," said Li. "Due to the existence of localization states, the charge carriers will mainly be captured in the localization states rather than by nonradiative recombination defects. This improves the high luminescence efficiency of light-emitting devices."
Based on the group's electroluminescence spectra, "the InGaN sample with stronger localization states provides more than a twofold enhancement of the light-output at the same current-injection conditions as samples of weaker localization states," Li said.
The researchers' work can serve as a reference for the emission properties of InGaN materials used in the manufacture of LEDs and laser diodes. They now plan to continue to explore gallium nitride-related materials and devices. "Not only to gain a better understanding of their localizations but also the properties of InGaN quantum dots, which are semiconductor particles with potential applications in solar cells and electronics," Li said. "We hope that other researchers will also conduct in-depth theoretical studies of localization states."
This story is adapted from material from the American Institute of Physics, with editorial changes made by Materials Today. The views expressed in this article do not necessarily represent those of Elsevier. Link to original source.