Like an opera singer hitting a note that shatters a glass, a signal at a particular resonant frequency can concentrate energy in a material and change its properties. And as with 18th century "musical glasses," adding a little water can change the critical pitch. Echoing both phenomena, researchers at the National Institute of Standards and Technology (NIST) have demonstrated a unique fluid-tuned "metasurface," a concept that may be useful in biomedical sensors and microwave-assisted chemistry.
 
A metasurface or metafilm is a two-dimensional version of a metamaterial, popularized recently in technologies with seemingly unnatural properties, such as the illusion of invisibility. Metamaterials have special properties not found in nature because of their novel structures. NIST's metasurface is a small piece of composite circuit board studded with metal patches in specific geometries and arrangements to create a structure that can reflect, store, or transmit energy.
 
As described in a new paper, NIST researchers used purified water to tune the metasurface's resonant frequency: the specific microwave frequency at which the surface can accumulate or store energy. They also calculated that the metasurface could concentrate an electric field in localized areas, and thus might be used to heat fluids and promote microwave-assisted chemical or biochemical reactions.
 
The metasurface's behavior is due to interactions of 18 square copper frame structures. Computer simulations helped design the copper squares to respond to a specific frequency. They are easily excited by microwaves, and each one can store energy in a T-shaped gap in its midsection when the metasurface is in a resonant condition. Fluid channels made of plastic tubing are bonded across the gaps. The sample is placed in a waveguide, which directs the microwaves and acts like a kaleidoscope, with walls that serve as mirrors and create the electrical illusion that the metasurface extends to infinity.
 
Researchers tested the metasurface properties with and without purified water in the fluid channels. The presence of water shifted the resonant frequency from 3.75 to 3.60 gigahertz. At other frequencies, the metasurface reflected or transmitted energy.
 
Metasurface/fluid interactions might be useful for tunable surfaces, sensing and process monitoring linked to changes in fluid flow, and catalysis of chemical or biochemical reactions in fluid channels controlled by changes in microwave frequency and power as well as fluid flow rates. NIST researchers are also looking into the possibility of making metamaterial chips or circuits for use in biomedical applications, such as counting cells.
 
This story is reprinted from material from NIST, with editorial changes made by Materials Today. The views expressed in this article do not necessarily represent those of Elsevier.