New state of matter is both solid and liquid

"We have shown that this unusual but stable state is part solid and part liquid. Recreating this unusual state in other materials could have all kinds of applications."Andreas Hermann, University of Edinburgh

Scientists have discovered a new state of physical matter in which atoms can exist as both solid and liquid simultaneously.

Until now, the atoms in physical material were understood to exist typically in one of three states – solid, liquid or gas. Recently, however, researchers have found that some elements, when subjected to extreme conditions, can take on the properties of both solid and liquid states.

Applying high pressures and temperatures to potassium creates a state in which most of the element's atoms form a solid lattice structure. However, the structure also contains a second set of potassium atoms that are in a fluid arrangement. Under the right conditions, over half a dozen elements – including sodium and bismuth – are thought to be capable of existing in the newly discovered state, researchers say.

Until now, it was unclear if the unusual structures represented a distinct state of matter, or existed as transition stages between two distinct states.

A team led by scientists at the University of Edinburgh in the UK has now used powerful computer simulations to study the existence of the state – known as the chain-melted state. Simulating how up to 20,000 potassium atoms behave under extreme conditions confirmed that the structures formed represent a new, stable state of matter.

Applying pressure to the atoms leads to the formation of two interlinked solid lattice structures, the team says. Chemical interactions between atoms in one lattice are strong, causing them to stay in a solid form when the structure is heated, while the other atoms melt into a liquid state.

The study, reported in a paper in the Proceedings of the National Academy of Sciences, was supported by the European Research Council and the UK Engineering and Physical Sciences Research Council. The work was carried out in collaboration with scientists from Xi'an Jiantong University in China.

"Potassium is one of the simplest metals we know, yet if you squeeze it, it forms very complicated structures," said Andreas Hermann of the University of Edinburgh's School of Physics and Astronomy, who led the study. "We have shown that this unusual but stable state is part solid and part liquid. Recreating this unusual state in other materials could have all kinds of applications."

This story is adapted from material from the University of Edinburgh, with editorial changes made by Materials Today. The views expressed in this article do not necessarily represent those of Elsevier. Link to original source.