At first, the atoms of molybdenum and sulphur are randomly distributed on the graphene membrane (left), but after being manipulated with the electron beam, they form regular crystal structures (right). Image: TU Wien.Among the thinnest structures on earth, two dimensional (2D) materials are crystals that consist of only one or a few layers of atoms. They often display unusual properties, promising many new applications in opto-electronics and energy technology. One of these 2D materials is molybdenum sulphide, an atomically thin layer of molybdenum and sulphur atoms.
The production of such ultra-thin crystals is difficult, however, as the crystallization process depends on many different factors. In the past, different synthesis techniques have yielded quite diverse results, but the reasons for this could not be accurately explained. Thanks to a new method developed by research teams at the Vienna University of Technology (TU Wien), the University of Vienna and Joanneum Research in Styria, all in Austria, for the first time ever it is now possible to observe the crystallization process directly under the electron microscope. The new method is described in a paper in ACS Nano.
"Molybdenum sulphide can be used in transparent and flexible solar cells or for sustainably generating hydrogen for energy storage," says the lead author of the study, Bernhard Bayer from the Institute of Materials Chemistry at TU Wien. "In order to do this, however, high-quality crystals must be grown under controlled conditions."
Usually this is done by starting out with atoms in gaseous form and then condensing them on a surface in a random and unstructured way. In a second step, the atoms are arranged in a regular crystal form – through heating, for example. "The diverse chemical reactions during the crystallization process are, however, still unclear, which makes it very difficult to develop better production methods for 2D materials of this kind," Bayer states.
Thanks to the new method, it should now be possible to accurately study the details of the crystallization process. "This means it is no longer necessary to experiment through trial and error, but thanks to a deeper understanding of the processes, we can say for certain how to obtain the desired product," Bayer adds.
In this new method, molybdenum and sulphur are first placed randomly on a membrane made of graphene. Graphene is probably the best known 2D material – a crystal with a thickness of only one atom layer consisting of carbon atoms arranged in a honeycomb lattice. The randomly arranged molybdenum and sulphur atoms are then manipulated in the electron microscope with a fine electron beam, which can simultaneously initiate the crystallization process and image it.
This makes it possible for the first time to directly observe how the atoms move and rearrange during the growth of the material with a thickness of only two atomic layers. "In doing so, we can see that the most thermodynamically stable configuration doesn't necessarily always have to be the final state," Bayer says.
Different crystal arrangements compete with one another, transform into each other and replace one another. "Therefore, it is now clear why earlier investigations had such varying results. We are dealing with a complex, dynamic process," Bayer explains. The new findings will help in adapting the structure of 2D materials more precisely to application requirements by influencing the rearrangement processes in a targeted manner.
This story is adapted from material from TU Wien, with editorial changes made by Materials Today. The views expressed in this article do not necessarily represent those of Elsevier. Link to original source.