An artistic rendition of the intriguing superionic crystalline structure of CuCrSe2, which possesses copper ions that move like liquid between solid layers of chromium and selenium, giving rise to useful electrical properties. Image: Oak Ridge National Laboratory/Jill Hemman.Materials scientists have sussed out the physical phenomenon underlying the promising electrical properties of a class of materials called superionic crystals. A better understanding of such materials could lead to safer and more efficient rechargeable batteries.
Becoming a popular topic of study only within the past five years, superionic crystals are a cross between a liquid and a solid. While some of their molecular components retain a rigid crystalline structure, others become liquid-like above a certain temperature, and are able to flow through the solid scaffold.
In a new study, scientists from Duke University, Oak Ridge National Laboratory (ORNL) and Argonne National Laboratory (ANL) probed one such superionic crystal made of copper, chromium and selenium (CuCrSe2) with neutrons and X-rays to determine how the material's copper ions achieve their liquid-like properties. They report their findings in a paper in Nature Physics.
"When CuCrSe2 is heated above 190°F, its copper ions fly around inside the layers of chromium and selenium about as fast as liquid water molecules move," said Olivier Delaire, associate professor of mechanical engineering and materials science at Duke and senior author of the paper. "And yet, it's still a solid that you could hold in your hand. We wanted to understand the molecular physics behind this phenomenon."
To probe the copper ions' behavior, Delaire and his colleagues turned to two world-class facilities: the Spallation Neutron Source at ORNL and the Advanced Photon Source at Argonne. Each instrument provided a unique piece of the puzzle.
By pinging a large sample of powdered CuCrSe2 made at ORNL with powerful neutrons, the researchers were able to obtain a wide-scale view of the material's atomic structure and dynamics. This revealed the vibrations of the stiff scaffold of chromium and selenium atoms, as well as the random jumps of copper ions within.
For a narrower but more detailed look at the vibration modes, the researchers bombarded a single grain of CuCrSe2 crystal with high-resolution X-rays. This allowed them to examine how the rays scattered off its atoms and how scaffold vibrations allowed shear waves to propagate, a hallmark of solid behavior.
With both sets of information in hand, Delaire's group ran quantum simulations of the material's atomic behavior at the National Energy Research Scientific Computing Center to explain their findings. These simulations revealed that, below the phase transition temperature of 190°F, the copper atoms vibrate around isolated sites, trapped in pockets of the material's scaffold structure. But above that temperature, they are able to hop randomly between multiple available sites. This allows the copper ions to flow throughout the otherwise solid crystal.
While more work is needed to understand how the copper atoms interact with one another once both sites become occupied, the findings offer clues as to how to use similar materials in future electronic applications.
"Most commercial lithium ion batteries use a liquid electrolyte to transfer ions between the positive and negative terminals of the battery," Delaire said. "While efficient, this liquid can be dangerously flammable, as many laptop and smartphone owners have unfortunately discovered.
"There are variants of superionic crystals that contain ions like lithium or sodium that behave like the copper in CuCrSe2. If we can understand how superionic crystals work through this study and future research, we could perhaps find a better, solid solution for transporting ions in rechargeable batteries."
This story is adapted from material from Duke University, with editorial changes made by Materials Today. The views expressed in this article do not necessarily represent those of Elsevier. Link to original source.