Tiny holes punched into the high-temperature superconducting material YBCO. Image: Valles lab/Brown University.
Tiny holes punched into the high-temperature superconducting material YBCO. Image: Valles lab/Brown University.

For years, physicists have assumed that Cooper pairs, the electron duos that allow superconductors to conduct electricity without resistance, were two-trick ponies. The pairs either glide freely, creating a superconducting state, or create an insulating state by jamming up within a material, unable to move at all.

But in a new paper in Science, a team of researchers report that Cooper pairs can also conduct electricity with some amount of resistance, just like regular metals do. These findings describe an entirely new state of matter, the researchers say, that will require a new theoretical explanation.

"There had been evidence that this metallic state would arise in thin-film superconductors as they were cooled down toward their superconducting temperature, but whether or not that state involved Cooper pairs was an open question," said Jim Valles, a professor of physics at Brown University and the paper's corresponding author. "We've developed a technique that enables us to test that question and we showed that, indeed, Cooper pairs are responsible for transporting charge in this metallic state. What's interesting is that no one is quite sure at a fundamental level how they do that, so this finding will require some more theoretical and experimental work to understand exactly what's happening."

Cooper pairs are named after Leon Cooper, a physics professor at Brown University, who won the Nobel Prize in 1972 for describing their role in producing superconductivity. Resistance is created when electrons rattle around in the atomic lattice of a material as they move. But when electrons join together to become Cooper pairs, they undergo a remarkable transformation.

Electrons by themselves are fermions, particles that obey the Pauli exclusion principle, which means each electron tends to keep to its own quantum state. Cooper pairs, however, act like bosons, which can happily share the same state. That bosonic behavior allows Cooper pairs to coordinate their movements with other sets of Cooper pairs in a way the reduces electrical resistance to zero.

In 2007, Valles, working with Brown engineering and physics professor Jimmy Xu, showed that Cooper pairs could produce insulating states as well as superconductivity. In very thin materials, instead of moving in concert, the pairs conspire to stay in place, stranded on tiny islands within a material and unable to jump to the next island.

For this new study, Valles, Xu and colleagues in China looked for Cooper pairs in a non-superconducting metallic state using a technique similar to the one that revealed Cooper pair insulators. This technique involves patterning a thin-film superconductor – in this case, the high-temperature superconductor yttrium barium copper oxide (YBCO) – with arrays of tiny holes. When the material has a current running through it and is exposed to a magnetic field, charge carriers in the material will orbit the holes like water circling a drain.

"We can measure the frequency at which these charges circle," Valles said. "In this case, we found that the frequency is consistent with there being two electrons going around at a time instead of just one. So we can conclude that the charge carriers in this state are Cooper pairs and not single electrons."

The idea that boson-like Cooper pairs are responsible for this metallic state is something of a surprise, the researchers say, because there are elements of quantum theory that suggest this shouldn't be possible. So understanding just what is happening in this state could lead to some exciting new physics, although more research will be required.

Luckily, the fact that this phenomenon was detected in a high-temperature superconductor will make future research more practical. YBCO starts superconducting at around -181°C, and the metallic phase starts at temperatures just above that. That's pretty cold, but it's much warmer than other superconductors, which are active at just above absolute zero (-273°C). That higher temperature makes it easier to use spectroscopy and other techniques aimed at better understanding what's happening in this metallic phase.

Down the road, the researchers say, it might be possible to harness this bosonic metal state for new types of electronic devices. "The thing about the bosons is that they tend to be in more of a wavelike state than electrons, so we talk about them having a phase and creating interference in much the same way light does," Valles said. "So there might be new modalities for moving charge around in devices by playing with interference between bosons."

But for now, the researchers are happy to have discovered a new state of matter. "Science is built on discoveries," Xu said, "and it's great to have discovered something completely new."

This story is adapted from material from Brown University, with editorial changes made by Materials Today. The views expressed in this article do not necessarily represent those of Elsevier. Link to original source.