Like turning coal to diamond, adding pressure to an electrical material enhances its properties. Now, University of Illinois at Urbana-Champaign researchers have devised a method of making ferroelectric thin films with twice the strain, resulting in exceptional performance.

Ferroelectric materials, metal oxides with special polarization properties, are used in a number of advanced electronics applications. When electricity is applied, they can switch their polarization, or the direction of their internal electric field, which makes them useful in devices such as computer memories and actuators. Ferroelectric materials are especially useful in aerospace applications because they are less susceptible to radiation than traditional semiconductors.

Strain in these materials can alter their properties and improve their performance. A lot of research in ferroelectric materials has focused on making strained thin films with alternating layers only a few nanometers thick of materials with slightly different crystal structures.

The films are made of lead zirconate titanate (commonly called PZT). The relative amounts of zirconium (Zr) and titanium (Ti) in the films determine the shape of the crystals. Traditionally, films of PZT have been made up of a single composition, grown on a substrate with a slightly different crystal structure to cause strain in the PZT. However, too much strain causes the PZT to revert to its original crystal structure. This limits researchers’ ability to change the properties of these materials for better device performance.

The Illinois researchers overcame this limitation by gradually shifting the concentrations of Zr and Ti as they grew the thin films, incrementally changing the crystal structure. From layer to layer, the structures are very similar, yet the composition of the PZT at the top and bottom of the film is very different, transitioning from a PZT composition with 80 percent Zr to 80 percent Ti. This gradual change, instead of the usual layered approach, results in little localized strain but large overall strain.

Thanks to the large strain, the compositionally graded PZT films not only have improved properties, but also entirely new properties. Most notably, the films have a built-in electric field, called an intrinsic potential. This means that it can perform some functions without needing an external current or field applied to it. In addition, it means that the material has a preferred polarity, which opens the door for new applications.

For example, ferroelectric materials widely have been used in memory applications that rely on spontaneous polarization. However, to read a bit of data in computer memories made with a traditional ferroelectric material, its polarity is switched. This means that every time the bit is read, it has to be re-written and compared to a reference bit. But if the material had a built-in electric potential, engineers could make bits that would not need to have their polarity switched to be read, so computer components made with the new material could be smaller, faster and longer lasting.

Now the Illinois team plans to further explore potential applications, as well as apply their gradient film technique to other types of ferroelectric materials in search of even more novel and unexpected properties.

This story is reprinted from material from
University of Illinois, with editorial changes made by Materials Today. The views expressed in this article do not necessarily represent those of Elsevier. Link to original source.