First look inside a working lithium-ion battery

For the first time, researchers have been able to open a kind of window into the inner workings of a lithium-ion battery.

Using a neutron beam, chemists and engineers at The Ohio State University were able to track the flow of lithium atoms into and out of an electrode in real time as a battery charged and discharged.

Ohio State researchers are using the technique to test new, high-capacity electrode materials, including ones containing tin, silicon, germanium and aluminum. These alternative electrodes could be capable of storing nearly three times as much energy as graphite, the material of choice in current lithium-ion batteries. They may also be less prone to overheating.

Until now, Marcello Canova explained, researchers could only measure a lithium-ion battery’s output (in voltage and current) and then make computer models of what might be going on inside—a process that he likened to “trying to study the combustion processes in a car engine when all you can do is measure the torque and speed at the wheels.”

“This is the first time that anyone has been able to directly verify how the lithium concentration evolves in space and time within the electrode of a live battery cell containing a typical wet electrolyte,” he said.

“We believe this will pave the way to an improved understanding of the material and chemical processes that power batteries.”

NDP is a well-known technique in nuclear research. It’s also used in the semiconductor industry, where it measures the concentration of dopants in silicon wafers. The Ohio State team is the first to further develop NDP into a tool to investigate lithium transport phenomena in normal, working batteries during charging and discharging.

NDP works in a way somewhat analogous to an MRI, in that it non-invasively captures images of an object’s interior. In the same way an MRI can record a series of image slices over time to capture changes in moving tissue, such as the inflation of a lung while a person is breathing, NDP can measure how the composition of a slice of material changes over time.

The images they’ve obtained thus far are two-dimensional, but with further development, 3D imaging might be possible. But whereas an MRI subjects materials to a magnetic field and measures how the polarity of the atoms in that material change, NDP hits materials with a low-energy neutron beam and counts the different kinds of charged particles that are created when an individual neutron happens to collide with one of the atoms in the test material and annihilates it.

“This is the first time that anyone has been able to directly verify how the lithium concentration evolves in space and time within the electrode of a live battery cell containing a typical wet electrolyte.”Marcello Canova , assistant professor of mechanical and aerospace engineering at Ohio State.

Lithium-ion batteries are popular in cars and handheld electronics because they are light and powerful, though their charge capacity still fades over time.

“One possible explanation for the fading is that lithium is becoming trapped inside the electrodes, and NDP would be an ideal method to see and quantify trapped lithium,” a researcher said.

The researchers measured the concentration of lithium in the battery anode—the negative electrode where positively charged lithium flows in as the battery charges, and out as the battery discharges. Normally, anodes in lithium-ion batteries are made of graphite, but for this experiment, the researchers replaced the graphite with a tin alloy.

Though NDP’s annihilation of lithium atoms doesn’t sound very non-invasive, Cao explained that these low-energy neutron collisions very rarely happen, and therefore couldn’t interfere with the normal performance of the battery.

In a working lithium-ion battery, the lithium must flow through a liquid electrolyte that fills the space between the cathode and anode—and that fact alone created the experiment’s main challenge. NDP only works inside a vacuum chamber, and vacuums vaporize liquids. That’s why another group of researchers in a 2011 study used a solid-state battery—that is, one in which the electrolyte was made from solid material.“We could hit it with a trillion neutrons per square centimeter, and the beam would still only consume one in a billion lithium atoms inside the battery,” the researcher said. “However, it is the capture of that one-in-a-billion reaction that tells us where the lithium ions are and how many.”

In the future, the team will try to identify the factors that cause lithium to become trapped in anodes, and investigate new materials that might lessen the effect. Along the way, they hope to find ways to boost overall charge capacity. Aside from battery studies, the researchers say that NDP also holds promise for examining certain materials for solar cells and catalysts, including materials that are used to treat nuclear waste.

This story is reprinted from material from The Ohio State University, with editorial changes made by Materials Today. The views expressed in this article do not necessarily represent those of Elsevier. Link to original source.