An international research team has discovered a potentially clean, low-cost way to convert carbon dioxide into methanol, a key ingredient in the production of plastics, adhesives and solvents, and a promising fuel for transportation.
Scientists from Stanford University, SLAC National Accelerator Laboratory and the Technical University of Denmark combined theory and experimentation to identify a new nickel-gallium catalyst that converts hydrogen and carbon dioxide into methanol with fewer side-products than the conventional catalyst.
"Methanol is processed in huge factories at very high pressures using hydrogen, carbon dioxide and carbon monoxide from natural gas," said study lead author Felix Studt, a staff scientist at SLAC. "We are looking for materials than can make methanol from clean sources, such as sunshine, under low-pressure conditions, while generating low amounts of carbon monoxide."
The ultimate goal is to develop a large-scale manufacturing process that is nonpolluting and carbon neutral using clean hydrogen, the author said.
Once he and his colleagues understood methanol synthesis at the molecular level, they began the hunt for a new catalyst capable of synthesizing methanol at low pressures using only hydrogen and carbon dioxide. Instead of testing a variety of compounds in the lab, Studt searched for promising catalysts in a massive computerized database that he and co-author Frank Abild-Pedersen developed at SLAC.
"We are looking for materials than can make methanol from clean sources..."Felix Studt, scientist at SLAC
"The technique is known as computational materials design," explained Nørskov, the director of the SUNCAT Center for Interface Science and Catalysis at Stanford and SLAC. "You get ideas for new functional materials based entirely on computer calculations. There is no trial-and-error in the lab first. You use your insight and enormous computer power to identify new and interesting materials, which can then be tested experimentally."
Studt compared the copper-zinc-aluminum catalyst with thousands of other materials in the database. The most promising candidate turned out to be a little-known compound called nickel-gallium.
Nørskov turned to a research group at the Technical University of Denmark led by Ib Chorkendorff, a co-author of the research paper. First, the Danish team carried out the task of synthesizing nickel and gallium into a solid catalyst. Then the scientists conducted a series of experiments to see if the new catalyst could actually produce methanol at ordinary room pressure.
The lab tests confirmed that the computer had made the right choice. At high temperatures, nickel-gallium produced more methanol than the conventional copper-zinc-aluminum catalyst, and considerably less of the carbon monoxide byproduct.
"You want to make methanol, not carbon monoxide," Chorkendorff said. "You also want a catalyst that's stable and doesn't decompose. The lab tests showed that nickel-gallium is, in fact, a very stable solid."
While these results show promise, a great deal of work lies ahead. "We'd like to make the catalyst a little more clean," Chorkendorff added. "If it contains just a few nanoparticles of pure nickel, the output drops quite a bit, because pure nickel is lousy at synthesizing methanol. In fact, it makes all sorts of chemical byproducts that you don't want."
Nickel is relatively abundant, and gallium, although more expensive, is widely used in the electronics industry. This suggests that the new catalyst could eventually be scaled up for industrial use, according to the authors. But to make methanol synthesis a truly carbon-neutral process will require overcoming many additional hurdles, they noted.
This story is reprinted from material from Stanford University, with editorial changes made by Materials Today. The views expressed in this article do not necessarily represent those of Elsevier. Link to original source.