Red phosphorus watches out for dendrites in lithium metal batteries

Scientists at Rice University have taken the next step toward the deployment of powerful, rechargeable lithium metal batteries by making them safer and simpler to manufacture.

The Rice lab of chemist James Tour made test cells incorporating a coat of red phosphorus on the separator that keeps the anode and cathode electrodes apart. The phosphorus acts as a spy for management systems used to charge and monitor batteries, by detecting the formation of dendrites, protrusions of lithium that can cause the batteries to fail.

Lithium metal anodes charge much faster and hold about 10 times more energy by volume than conventional lithium-ion anodes, which are used in just about every electronic device on the market, including cellphones and electric cars. Anodes are one of two electrodes needed for battery operation.

But charging lithium-infused anodes creates dendrites that, if they reach the cathode, cause a short circuit and possibly a fire or explosion. By contrast, when a dendrite reaches a red phosphorus-coated separator, the battery's charging voltage changes. That tells the battery management system to stop charging.

Unlike other proposed dendrite detectors, the Rice strategy doesn't require a third electrode. "Manufacturing batteries with a third electrode is very hard," Tour said. "We propose a static layer that gives a spike in the voltage while the battery is charging. That spike is a signal to shut it down." Tour and his colleagues report their research in a paper in Advanced Materials.

Experiments conducted by the Tour lab on test batteries revealed that the red phosphorus layer had no significant effect on normal performance. The researchers also built a transparent test cell containing an electrolyte (the liquid or gel-like material between the electrodes and around the separator that allows the battery to generate a current) known to accelerate aging of the cathode and encourage dendrite growth. This let them monitor the voltage while they watched dendrites grow.

With an ordinary separator, they saw the dendrites contact and penetrate the separator with no change in voltage, a situation that would lead a normal battery to fail. But with the red phosphorus layer, they observed a sharp drop in voltage when the dendrites contacted the separator.

"As soon as a growing dendrite touches the red phosphorus, it gives a signal in the charging voltage," Tour said. "When the battery management system senses that, it can say, 'Stop charging, don't use'."

Last year, Tour’s lab introduced carbon nanotube films that appear to completely halt dendrite growth from lithium metal anodes (see Carbon nanotube film stops dendrites in their tracks). "By combining the two recent advances, the growth of lithium dendrites can be mitigated, and there is an internal insurance policy that the battery will shut down in the unlikely event that even a single dendrite will start to grow toward the cathode," Tour said.

"Literally, when you make a new battery, you're making over a billion of them. Might a couple of those fail? It only takes a few fires for people to get really antsy. Our work provides a further guarantee for battery safety. We're proposing another layer of protection that should be simple to implement."

This story is adapted from material from Rice University, with editorial changes made by Materials Today. The views expressed in this article do not necessarily represent those of Elsevier. Link to original source.