Novel twist on ferroelectricity

A team of researchers at the University of Manchester’s National Graphene Institute (NGI) and the National Physical Laboratory (NPL), both in the UK, has demonstrated that slightly twisted 2D transition metal dichalcogenides (TMDs) can display room-temperature ferroelectricity.

This characteristic, combined with TMDs’ outstanding optical properties, could be used to build multi-functional optoelectronic devices such as transistors and LEDs with built-in memory functions on nanometer length scales.

Ferroelectrics are materials with two or more electrically polarizable states that can be reversibly switched by applying an external electric field. This material property is ideal for applications such as non-volatile memory, microwave devices, sensors and transistors. Until recently, out-of-plane switchable ferroelectricity at room temperature had only been achieved in films thicker than 3nm.

Since the isolation of graphene in 2004, researchers across academia have studied a variety of new two-dimensional (2D) materials with a wide range of exciting properties. These atomically thin 2D crystals can be stacked on top of one another to create so-called heterostructures – artificial materials with tailored functions – and twisting these crystal layers with respect to each other can introduce even more exciting properties, including superconductivity.

Recently, a team of researchers from NGI, in collaboration with NPL, demonstrated that below a twist angle of 2°, atomic lattices physically reconstruct to form regions (or domains) of perfectly stacked bilayers separated by boundaries of locally accumulated strain. For two monolayers stacked parallel to each other, a tessellated pattern of mirror-reflected triangular domains is created. Most importantly, the two neighbouring domains have an asymmetric crystal symmetry, causing an asymmetry in their electronic properties.

In the latest work, reported in a paper in Nature Nanotechnology, the team demonstrated that the domain structure created with low-angle twisting hosts interfacial ferroelectricity in bilayer TMDs. Kelvin probe force microscopy (KPFM) revealed that neighbouring domains are oppositely polarized and electrical transport measurements demonstrated reliable ferroelectric switching at room temperature.

The researchers went on to develop a scanning electron microscope (SEM) technique with enhanced contrast, using signal from back-scattered electrons. This allowed them to apply an electric field in-situ while imaging changes to the domain structure in a non-invasive manner, providing essential information on how the domain switching mechanism works. The boundaries separating the oppositely polarized domains were found to expand and contract depending on the sign of the applied electric field and led to a significant redistribution of the polarized states.

This work clearly demonstrates that the twist degree of freedom can allow the creation of atomically thin optoelectronics with tailored and multi-functional properties.

“It’s very exciting that we can demonstrate that this simple tool of twisting can engineer new properties in 2D crystals,” said lead author Astrid Weston from NGI. “With the wide variety of 2D crystals to choose from, it provides us with almost unlimited scope to create perfectly tailored artificial materials.”

“Being able to observe the pattern and behaviour of ferroelectric domains in structures that have nanometer thickness with KPFM and SEM was very exciting,” said co-author Eli Castanon from NPL. “The advancement of characterization techniques together with the extensive possibilities for the formation of novel heterostructures of 2D materials paves the way to achieve new capabilities at the nanoscale for many industries.”

This story is adapted from material from the University of Manchester, with editorial changes made by Materials Today. The views expressed in this article do not necessarily represent those of Elsevier. Link to original source.