Organic photodiodes can be much larger than their silicon counterparts. On the left is a silicon photodiode, and on the right are two large-area organic photodiodes. Photo: Canek Fuentes-Hernandez, Georgia Tech.
Organic photodiodes can be much larger than their silicon counterparts. On the left is a silicon photodiode, and on the right are two large-area organic photodiodes. Photo: Canek Fuentes-Hernandez, Georgia Tech.

New research shows the performance of flexible large-area organic photodiodes has now advanced to the point where they can offer advantages over conventional silicon photodiode technology, particularly for applications such as biomedical imaging and biometric monitoring that require detecting low levels of light across large areas.

Low-noise, solution-processed, flexible organic devices developed by researchers at the Georgia Institute of Technology offer the ability to use arbitrarily shaped, large-area photodiodes to replace the complex arrays that would be required with conventional silicon photodiodes, which can be expensive to scale up for large-area applications. These organic devices provide performance comparable to that of rigid silicon photodiodes in the visible light spectrum – except in response time.

"What we have achieved is the first demonstration that these devices, produced from solution at low temperatures, can detect as little as a few hundred thousand photons of visible light every second, similar to the magnitude of light reaching our eye from a single star in a dark sky," said Canek Fuentes-Hernandez, principal research scientist in the School of Electrical and Computer Engineering at Georgia Tech. "The ability to coat these materials onto large-area substrates with arbitrary shapes means that flexible organic photodiodes now offer some clear advantages over state-of-the-art silicon photodiodes in applications requiring response times in the range of tens of microseconds."

The development and performance of these large-area, low-noise organic photodiodes are described by Fuentes-Hernandez and his colleagues in a paper in Science. The research was supported by multiple US organizations, including the Office of Naval Research, the Air Force Office of Scientific Research, and the Department of Energy's National Nuclear Security Administration.

Organic electronic devices are based on materials fabricated from carbon-based molecules or polymers, rather than conventional inorganic semiconductors such as silicon. The devices can be made using simple solution and inkjet printing techniques instead of the expensive and complex processes involved in the manufacturing of conventional electronics. The technology is now widely used in displays, solar cells and other devices.

The organic photodiodes developed by Fuentes-Hernandez and his colleagues utilize polyethylenimine, an amine-containing polymer surface modifier found to produce air-stable, low work-function electrodes in photovoltaic devices developed in the laboratory of Bernard Kippelen, a professor at Georgia Tech. The use of polyethylenimine was also shown to produce photovoltaic devices with low levels of dark current – the electrical current that flows through a device even in the dark. This meant the materials could be useful in photodetectors for capturing faint signals of visible light.

"Over the years, the dark current levels were reduced so much that measurement equipment had to be redesigned to detect an electronic noise corresponding to a fluctuation of one electron in one millionth of a second," said Fuentes-Hernandez. "This work reflects sustained team efforts made in the Kippelen group over more than six years and encompasses part of the PhD work of recent graduates Talha Kahn and Wen-Fang Chou. These collective efforts produced the scientific insights needed to demonstrate organic photodiodes with this level of performance."

One application for the new devices is in pulse oximeters, which are placed on fingers to measure heart rate and blood oxygen levels. Organic photodiodes may allow multiple devices to be placed on the body and operate with 10 times less light than conventional devices. This could allow wearable health monitors to produce improved physiological information and continuous monitoring without frequent battery changes. Other potential applications include human-computer interfaces such as touchless gesture recognition and controls.

Another future application is detection of ionizing radiation by scintillation – a flash of light emitted by a phosphor when struck by a high energy particle. Lowering the level of light that can be detected would improve the sensitivity of the device, allowing it to detect lower levels of radiation. Detecting radiation emitted from vehicles or cargo containers requires a large detector area, which would be easier to make from organic photodiodes than from arrays of silicon photodiodes.

Organic photodiodes could offer similar advantages for X-ray equipment, where doctors want to use the smallest level of radiation possible to minimize the dose delivered to the patient. Here again, sensitivity, large area and flexible form factor should give organic photodiodes an advantage over silicon-based arrays.

Key performance factors of the organic photodiodes compare well with silicon except in the area of response time, where researchers are working on a hundred-fold improvement for future applications.

"We are working on improving the response time of the photodetector because producing fast photodetectors would enable many additional important applications," Fuentes-Hernandez said. "There's a real need to develop photodetector technologies that are more scalable, and one of the motivations of this work is to advance organic technology that we know is cost effective for scaling."

"Because we use materials that are processed from inks using printing techniques, they are not as ordered as crystalline materials," Kippelen added. "As a result, the carrier mobility and the velocity of the carriers that can move through these materials are lower, so you can't get the same fast signals you get with silicon. But for many applications you don't need picosecond or nanosecond response time."

For Kippelen, the photodiode work shows the results of a 25-year effort to improve the performance of organic electronic materials. That work, part of Georgia Tech's Center for Organic Photonics and Electronics, has involved extensive device modeling to understand the basic science, and research to continuously boost the performance of the materials.

"Organic thin films absorb light more efficiently than silicon, so the overall thickness you need to absorb that light is very small," Kippelen said. "Even if you scale their area up, the overall volume of your detector remains small with organics. If you increase the area of a silicon detector, you have a larger volume of materials that at room temperature will generate a lot of electronic noise."

The photodiodes made in Kippelen's lab employ an active layer just 500nm thick. A gram of the material, roughly the size of a fingertip, could coat the surface of an office desk.

Kippelen hopes the Science paper will help open new doors for organic semiconductors. "Advances like this will allow us to change the conventional wisdom that switching to organic materials that can lead to scalable devices would mean giving up performance," he said. "We can't anticipate all the new applications that could be enabled by this advance."

This story is adapted from material from Georgia Institute of Technology, with editorial changes made by Materials Today. The views expressed in this article do not necessarily represent those of Elsevier. Link to original source.