This illustration shows how the layers of plastic and silica work together to protect the perovskite material. Image: Georgia Tech.Perovskite nanocrystals hold promise for improving a wide variety of optoelectronic devices – from lasers to light-emitting diodes (LEDs) – but problems with their durability still limit the material's broad commercial use.
Researchers at the Georgia Institute of Technology have now demonstrated a novel approach aimed at addressing the material's durability problem, which involves encasing the perovskite inside a double-layer protection system made from plastic and silica. In a paper in Science Advances, the research team describes a multistep process for producing encased perovskite nanocrystals that exhibit strong resistance to degradation in moist environments.
"Perovskite nanocrystals are highly susceptible to degradation, particularly when they come into contact with water," said Zhiqun Lin, a professor in the Georgia Tech School of Materials Science and Engineering. "This dual-shelled system offers two layers of protection while allowing each nanocrystal to remain a distinct and separate unit, achieving the maximum amount of surface area and other physical characteristics of the perovskite needed for optimizing optoelectronic applications."
The term perovskite refers to the crystal structure of the material, which is generally composed of three parts: two cations of different sizes and an anion in between. For decades, researchers have tried substituting various chemicals into this structure to achieve unique characteristics. In particular, perovskites that contain halide compounds such as bromide and iodine can act as light absorbers and emitters.
For this study, Lin's group worked with one of the most common halide configurations, comprising methylammonium, lead and bromide. First, they formed star-shaped plastic molecules that could serve as ‘nanoreactors’, by growing 21 polymer arms on a simple sugar molecule. Then, once precursor chemicals for the silica and perovskite nanocrystals are loaded onto the plastic molecule, several stages of chemical reactions produce the final system.
After the star-shaped plastic has played its role as a nanoreactor, the star-shaped components remain permanently attached to the silica, almost like hair encasing the perovskite. These hairs serve as the first layer of protection, repelling water and preventing the nanocrystals from clumping together. The subsequent layer of silica adds further protection should any water get past the water-repelling plastic hair.
"Synthesis and applications of perovskite nanocrystals have been a rapidly evolving research field over the past five years," said Yanjie He, a co-author of the paper and former graduate student at Georgia Tech. "Our strategy, based on a judiciously designed star-shaped plastic as a nanoreactor, enables unprecedented control in the crafting of high-quality perovskite nanocrystals with complex architecture, which is inaccessible in conventional approaches."
To test the material, the researchers coated glass substrates with a thin film of the encapsulated perovskites and conducted several stress tests, including immersing the entire sample in deionized water. By shining ultraviolet light upon the sample, they found that the photoluminescent properties of the encapsulated perovskites didn’t diminish at all during a 30-minute test. For comparison, the researchers also immersed unencapsulated perovskites in water and watched as their photoluminescence vanished in a matter of seconds.
Lin said this new method offers the possibility of tuning the surface characteristics of the dual-shelled nanocrystal to enhance its performance in a greater range of applications. The process of fabricating the new perovskite nanocrystals from the star-shaped plastic was also unique, as it employed low-boiling point solvents with low toxicity. Future research may focus on developing different perovskite nanocrystal systems, including all-inorganic perovskites, double perovskites and doped perovskites.
"We envision that this type of perovskite nanocrystal will prove very useful for creating durable optoelectronic devices for bioimaging, biosensors, photonic sensors and radiation detection, as well as next generation LEDs, lasers and scintillators," Lin said. "This is because these hairy perovskite nanocrystals carry unique advantages, including high defect tolerance, narrower emission bands and high scintillation efficiency."
This story is adapted from material from the Georgia Institute of Technology, with editorial changes made by Materials Today. The views expressed in this article do not necessarily represent those of Elsevier. Link to original source.