This illustrates the process by which ALD was used to coat a hydrophobic polymeric membrane with titanium dioxide. First, the researchers dip-coated the membrane in tannic acid (TA), a common polyphenol. Then, the dried TA-dip-coated membrane was loaded into the ALD reactor for coating with titanium dioxide using the precursors titanium tetrachloride and water. The coated membranes displayed minimal fouling during oil-in-water treatment. Image: Argonne National Laboratory.Many industrial processes rely on thin membranes that can clean water, such as by filtering out impurities. In recent years, a technique called atomic layer deposition (ALD) has been used to tune these membranes for better performance, but there's a hitch. Many of the membranes are made from materials that aren't compatible with ALD, which uses alternating chemical vapors to create very thin layers on a surface.
A new method developed by a team that included researchers from the US Department of Energy (DOE)'s Argonne National Laboratory now makes ALD possible on nearly any membrane. The researchers discovered a surprisingly simple solution: dip the membranes in tannic acid first. The acid's molecules stick to the membrane's surface, providing nucleation sites – or points where an ALD coating can take hold and grow.
The ability to use this technique on typically resistant membrane materials allows for a variety of potential enhancements that could improve functionality and durability – or create altogether new properties. The researchers report their work in a paper in Advanced Functional Materials.
Many commercial membranes are made from common plastics such as polypropylene and polyethylene, which are inexpensive and relatively sturdy. But when used to treat water, these polymer-based membranes tend to cause problems. Their surfaces are prone to fouling, where contaminants accumulate in their pores and reduce efficacy.
With ALD, a process common in the semiconductor industry, membranes can be altered to resist fouling or take on other desirable properties. Molecules deposited on the surface can weave their way through a membrane's tortuous network of pores to reach all the surfaces inside, creating an exceptionally uniform coating.
"ALD, in principle, is great," said Seth Darling, a co-author of the paper and director of Argonne's Advanced Materials for Energy-Water Systems (AMEWS) Energy Frontier Research Center. "The challenge is that most polymers that are used to make membranes are not amenable to coating with ALD."
In the study, tannic acid pretreatment allowed a water-resistant polymer membrane to be coated with titanium dioxide, transforming its surface so that it become hydrophilic (water-loving) instead. The water-attracting layer creates a protective buffer against fouling.
The AMEWS center, which is funded by DOE's Office of Science, supported the work as part of a broader effort to understand and control what happens at the interface between water and solid materials. Such understanding is key to improving how we process and use water.
In the past, Argonne researchers have exploited the fact that some polymers are inhospitable to ALD to create a two-faced ‘Janus’ membrane, with a full metal oxide coating on top of the membrane and none on the other side. This latest study is the first time that scientists have been able to completely and uniformly sensitize a membrane to ALD using a non-destructive pretreatment.
Argonne is developing methods for scaling up ALD and other interface engineering capabilities so that these methods can be evaluated for large, industrial applications. "We currently use lab-scale reactors for these research studies, but we are building tools for efficient ALD processing of large area substrates. This will allow pilot-scale testing of our ALD materials," said Jeffrey Elam, a senior chemist at Argonne and co-author of the paper.
The new method could potentially work not just with tannic acid but with any liquid polyphenol and also with any polymer membrane, which opens up a vast number of possibilities beyond the proof of concept described in the paper. In addition to water-attracting or water-resistant coatings, ALD can be used to create chemically reactive or electrically conductive materials.
"There's a whole library of things you can do with ALD," Darling said. "This technique now opens up that library for polymer membranes."
This story is adapted from material from Argonne National Laboratory, with editorial changes made by Materials Today. The views expressed in this article do not necessarily represent those of Elsevier. Link to original source.