(a) Illustration of multilayered graphene sheets, (b) cross-section illustration of multilayered MoS2 with an interlayer spacing of ~0.65 nm, (c) Exfoliated few-layer MoS2 and rGO flakes.
(a) Illustration of multilayered graphene sheets, (b) cross-section illustration of multilayered MoS2 with an interlayer spacing of ~0.65 nm, (c) Exfoliated few-layer MoS2 and rGO flakes.

Graphene and related inorganic two-dimensional (2D) nanomaterials are an exceptional class of compounds with exotic properties that are technologically intriguing. While graphene itself is chemically inert and a gapless semimetal, its isostructural analog, molybdenum disulfide (MOS2) is chemically versatile with band gaps, thereby finding significant use in a myriad of applications. Although these 2D nanomaterials individually possess tremendous authority for various applications, the combination of these materials in the recent past has created a new paradigm in emerging applications. Here, we summarize the current state-of-the-art and progress over the past three years on the development of hybrids of these layered materials. We highlight their pivotal role in electrochemical energy storage, sensing, hydrogen generation by photochemical water splitting and electronic device applications such as field-effect transistors. Perspectives on the challenges and opportunities for the exploration of these 2D layered hybrid materials are put forward.

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DOI: 10.1016/j.mattod.2015.01.016