Colossal magnetoresistance is a property with practical applications in a wide array of electronic devices including magnetic sensors and magnetic RAM. New research from a team including Carnegie's Maria Baldini, Ho-Kwang ‘Dave’ Mao, Takaki Muramatsu and Viktor Struzhkin successfully used high-pressure conditions to induce colossal magnetoresistance for the first time in a pure sample of lanthanum manganite (LaMnO3). This research appears in a paper in the Proceedings of the National Academy of Sciences.

Magnetoresistance is the ability of certain compounds to be changed from electrically resistant to electrically conductive depending on the presence of an external magnetic field. The ability to switch between insulator and metal is what makes the phenomenon so useful for electronic and spintronic devices.

Manganite compounds such as the LaMnO3 are particularly promising when it comes to colossal magnetoresistance, because the change from insulator to metal is several orders of magnitude stronger than in other types of compounds. But controlling and understanding it has remained largely elusive. Magnetoresistance has been induced in chemically-doped manganite samples, but not in a pure one, until this study.

The transition from insulator to metal in LaMnO3 takes place when it is exposed to extreme pressures: around 316,000 times normal atmospheric pressure (32 gigapascals). What the team was able to demonstrate by examining LaMnO3 across a range of temperatures and pressures is that under pressure LaMnO3 separates into two distinct phases, one metallic and one non-metallic. The chemical structure of the non-metallic phase is distorted, while the metallic phase is not.

The insulator-to-metal transition occurs when the metallic phase exceeds the non-metallic one by a certain threshold, as confirmed by theoretical predictions. But the existence of a period when the two phases are mixed together is the crucial ingredient for inducing colossal magnetoresistance. The phenomenon occurs when the competition between the two phases is at its maximum. The physical separation of the two phases and the interplay between the deformed structure and the non-deformed structures is the key to driving the colossal magnetoresistance.

"The ability to induce colossal magnetoresistance by applying pressure to a pure, un-doped sample is a major step forward in understanding the physics underlying the phenomenon and to potentially harnessing it for practical purposes," Baldini said.

This story is adapted from material from the Carnegie Institution, with editorial changes made by Materials Today. The views expressed in this article do not necessarily represent those of Elsevier. Link to original source.

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