When an island of inactivated lithium metal travels to a battery’s anode and reconnects, it comes back to life, contributing electrons to the battery’s current flow and lithium ions for storing charge until it’s needed. The island moves by adding lithium metal at one end (blue) and dissolving it at the other end (red). Image: Greg Stewart/SLAC National Accelerator Laboratory.Researchers at the US Department of Energy’s SLAC National Accelerator Laboratory and Stanford University may have found a way to revitalize rechargeable lithium batteries, potentially boosting the range of electric vehicles and the battery life in next-gen electronic devices.
As lithium batteries cycle, they accumulate little islands of inactive lithium that are cut off from the electrodes, decreasing the battery’s capacity to store charge. But the researchers discovered they could make this 'dead' lithium creep like a worm toward one of the electrodes until it reconnects, partially reversing the unwanted process. Adding this extra step slowed the degradation of their test battery and increased its lifetime by nearly 30%.
“We are now exploring the potential recovery of lost capacity in lithium-ion batteries using an extremely fast discharging step,” said Stanford postdoctoral fellow Fang Liu, the lead author of a paper on this work in Nature.
A great deal of research has been conducted into developing rechargeable batteries with lighter weight, longer lifetimes, improved safety and faster charging speeds than the lithium-ion technology currently used in cellphones, laptops and electric vehicles. A particular focus is on developing lithium-metal batteries, which can store more energy per volume or weight. For example, in electric cars, these next-generation batteries could increase the mileage per charge and possibly take up less trunk space.
Both battery types utilize positively charged lithium ions that shuttle back and forth between the electrodes. Over time, some of the metallic lithium becomes electrochemically inactive, forming isolated islands that no longer connect with the electrodes. This results in a loss of capacity, and is a particular problem for lithium-metal technology and for the fast charging of lithium-ion batteries.
In this new study, however, the researchers demonstrated they could mobilize and recover the isolated lithium to extend battery life.
“I always thought of isolated lithium as bad, since it causes batteries to decay and even catch on fire,” said Yi Cui, a professor at Stanford and SLAC, and an investigator with the Stanford Institute for Materials and Energy Research (SIMES), who led the research. “But we have discovered how to electrically reconnect this ‘dead’ lithium with the negative electrode to reactivate it.”
The idea for the study was born when Cui speculated that applying a voltage to a battery’s cathode and anode could make an isolated island of lithium physically move between the electrodes – a process his team has now confirmed with their experiments.
The scientists fabricated an optical cell with a lithium anode, a lithium-nickel-manganese-cobalt-oxide (NMC) cathode and an isolated lithium island in between. This test device allowed them to track in real time what happens inside a battery when in use.
They discovered that the isolated lithium island wasn’t 'dead' at all but responded to battery operations. When charging the cell, the island slowly moved towards the cathode; when discharging, it crept in the opposite direction.
“It’s like a very slow worm that inches its head forward and pulls its tail in to move nanometer by nanometer,” Cui said. “In this case, it transports by dissolving away on one end and depositing material to the other end. If we can keep the lithium worm moving, it will eventually touch the anode and re-establish the electrical connection.”
These results, which the scientists validated with other test batteries and through computer simulations, also demonstrate how isolated lithium could be recovered in a real battery by modifying the charging protocol.
“We found that we can move the detached lithium toward the anode during discharging, and these motions are faster under higher currents,” said Liu. “So we added a fast, high-current discharging step right after the battery charges, which moved the isolated lithium far enough to reconnect it with the anode. This reactivates the lithium so it can participate in the life of the battery.
“Our findings also have wide implications for the design and development of more robust lithium-metal batteries.”
This story is adapted from material from SLAC National Accelerator Laboratory, with editorial changes made by Materials Today. The views expressed in this article do not necessarily represent those of Elsevier. Link to original source.