Researchers have taken a step toward overcoming a key obstacle in commercializing "hyperbolic metamaterials," structures that could bring optical advances including ultrapowerful microscopes, computers and solar cells.

The researchers have shown how to create the metamaterials without the traditional silver or gold previously required, said Alexandra Boltasseva, a Purdue University assistant professor of electrical and computer engineering.

Using the metals is impractical for industry because of high cost and incompatibility with semiconductor manufacturing processes. The metals also do not transmit light efficiently, causing much of it to be lost. The Purdue researchers replaced the metals with an "aluminum-doped zinc oxide," or AZO.

"This means we can have a completely new material platform for creating optical metamaterials, which offers important advantages," Boltasseva said.

Light passing from the zinc oxide to the AZO layers encounters an "extreme anisotropy," causing its dispersion to become "hyperbolic," which dramatically changes the light's behavior.

"The doped oxide brings not only enhanced performance but also is compatible with semiconductors," Boltasseva said.

The list of possible applications for metamaterials includes a "planar hyperlens" that could make optical microscopes 10 times more powerful and able to see objects as small as DNA; advanced sensors; more efficient solar collectors; quantum computing; and cloaking devices.

The AZO also makes it possible to "tune" the optical properties of metamaterials, an advance that could hasten their commercialization, Boltasseva said.
"It's possible to adjust the optical properties in two ways," she said. "You can vary the concentration of aluminum in the AZO during its formulation. You can also alter the optical properties in AZO by applying an electrical field to the fabricated metamaterial."

This switching ability might usher in a new class of metamaterials that could be turned hyperbolic and non-hyperbolic at the flip of a switch.

"This could actually lead to a whole new family of devices that can be tuned or switched," Boltasseva said. "AZO can go from dielectric to metallic. So at one specific wavelength, at one applied voltage, it can be metal and at another voltage it can be dielectric. This would lead to tremendous changes in functionality."

The researchers "doped" zinc oxide with aluminum, meaning the zinc oxide is impregnated with aluminum atoms to alter the material's optical properties. Doping the zinc oxide causes it to behave like a metal at certain wavelengths and like a dielectric at other wavelengths.

The material has been shown to work in the near-infrared range of the spectrum, which is essential for optical communications, and could allow researchers to harness "optical black holes" to create a new generation of light-harvesting devices for solar energy applications.

This story is reprinted from material from Purdue University, with editorial changes made by Materials Today. The views expressed in this article do not necessarily represent those of Elsevier. Link to original source.