Artistic representation of QAVI shock absorbers. Image: Ella Maru Studio.
Artistic representation of QAVI shock absorbers. Image: Ella Maru Studio.

Semiconducting perovskites that exhibit superfluorescence at room temperature do so thanks to built-in thermal ‘shock absorbers’ that protect dipoles within the material from thermal interference. A new study by researchers at North Carolina State University (NS State) explores the mechanism behind this macroscopic quantum phase transition, and explains how and why materials like perovskites can exhibit macroscopic quantum coherence at high temperatures.

Picture a school of fish swimming in unison or the synchronized flashing of fireflies – examples of collective behavior in nature. When similar collective behavior happens in the quantum world – a phenomenon known as macroscopic quantum phase transition – it leads to exotic processes such as superconductivity, superfluidity and superfluorescenece. In all of these processes, a group of quantum particles forms a macroscopically coherent system that acts like a giant quantum particle.

Superfluorescence is a macroscopic quantum phase transition in which a population of tiny light-emitting units known as dipoles form a giant quantum dipole and simultaneously radiate a burst of photons. Similar to superconductivity and superfluidity, superfluorescence normally requires cryogenic temperatures to be observed, because at higher temperatures the dipoles move out of phase too quickly to form a collectively coherent state.

Recently, a team led by Kenan Gundogdu, professor of physics at NC State and corresponding author of a paper on this work in Nature Photonics, had observed superfluorescence at room temperature in hybrid perovskites. “Our initial observations indicated that something was protecting these atoms from thermal disturbances at higher temperatures,” Gundogdu says.

The team analyzed the structure and optical properties of a common lead-halide hybrid perovskite. They noticed the formation of polarons in this material – quasiparticles made of bound lattice motion and electrons. Lattice motion refers to a group of atoms that are collectively oscillating. When an electron binds to these oscillating atoms, a polaron forms.

“Our analysis showed that formation of large polarons creates a thermal vibrational noise filter mechanism that we call, ‘Quantum Analog of Vibration Isolation,’ or QAVI,” Gundogdu says.

“In layman’s terms, QAVI is a shock absorber,” explains Franky So, professor of materials science and engineering at NC State and co-author of the paper. “Once the dipoles are protected by the shock absorbers, they can synchronize and exhibit superfluorescence.”

According to the researchers, QAVI is an intrinsic property that exists in certain materials, like hybrid perovskites. However, understanding how this mechanism works could lead to quantum devices that operate at room temperature.

“Understanding this mechanism not only solves a major physics puzzle, it may help us identify, select and also tailor materials with properties that allow extended quantum coherence and macroscopic quantum phase transitions” Gundogdu says.

This story is adapted from material from North Carolina State University, with editorial changes made by Materials Today. The views expressed in this article do not necessarily represent those of Elsevier. Link to original source.