A green laser shines onto an atomically thin material. By probing how atoms vibrate when deposited on substrates and then heated, researchers have turned Raman spectroscopy into a scientific ‘ruler’ to understand how 2D materials expand. Image courtesy of Yang Zhong and Lenan Zhang.Two-dimensional materials, which consist of just a single layer of atoms, can be packed together more densely than conventional materials, and so could be used to make transistors, solar cells, LEDs and other devices that run faster and perform better.
One issue holding back these next-generation electronics is the heat they generate when in use. Conventional electronics typically reach about 80°C, but the materials in 2D devices are packed so densely in such a small area that the devices can become twice as hot. These high temperatures can damage the device.
This problem is compounded by the fact that scientists don’t have a good understanding of how 2D materials expand when temperatures rise. Because the materials are so thin and optically transparent, their thermal expansion coefficient (TEC) – the extent to which a material expands when temperatures increase — is nearly impossible to measure using standard approaches.
“When people measure the thermal expansion coefficient for some bulk material, they use a scientific ruler or a microscope, because with a bulk material you have the sensitivity to measure them,” says Yang Zhong, a graduate student in mechanical engineering at Massachusetts Institute of Technology (MIT). “The challenge with a 2D material is that we cannot really see them, so we need to turn to another type of ruler to measure the TEC.”
Together with colleagues at MIT and the Southern University of Science and Technology in China, Zhong has now developed just such a ‘ruler’, which is described in a paper in Science Advances. Rather than directly measuring how a 2D material expands, the researchers use laser light to track vibrations in the atoms that comprise the material. Taking measurements of one 2D material on three different surfaces, or substrates, allows them to accurately extract its thermal expansion coefficient.
The new study shows that this method is highly accurate, achieving results that match theoretical calculations. The approach confirms that the TECs of 2D materials fall into a much narrower range than previously thought. This information could help engineers design next-generation electronics.
“By confirming this narrower physical range, we give engineers a lot of material flexibility for choosing the bottom substrate when they are designing a device,” says Lenan Zhang, co-lead author and former MIT mechanical engineering graduate student, who is now a research scientist. “They don’t need to devise a new bottom substrate just to mitigate thermal stress. We believe this has very important implications for the electronic device and packaging community.”
Because 2D materials are so small – perhaps just a few microns in size – standard tools aren’t sensitive enough to directly measure their expansion. Plus, the materials are so thin they must be bonded to a substrate such as silicon or copper. If the 2D material and its substrate have different TECs, they will expand differently when temperatures increase, which causes thermal stress.
For instance, if a 2D material is bonded to a substrate with a higher TEC, the substrate will expand more when the device is heated, stretching the 2D material. This makes it difficult to measure the actual TEC of a 2D material since the substrate affects its expansion.
The researchers overcame these problems by focusing on the atoms that make up the 2D material. When a material is heated, its atoms vibrate at a lower frequency and move farther apart, which causes the material to expand. They measured these vibrations using a technique called micro-Raman spectroscopy, which involves hitting the 2D material with a laser. The vibrating atoms in the material scatter the laser’s light, and this interaction can be used to detect their vibrational frequency.
But as the substrate expands or compresses, it impacts how the 2D material’s atoms vibrate. The researchers needed to decouple this substrate effect to be able to zero in on the material’s intrinsic properties. They did this by measuring the vibrational frequency of the same 2D material on three different substrates: copper, which has a high TEC; fused silica, which has a low TEC; and a silicon substrate dotted with tiny holes. Because the 2D material hovers above the holes on the latter substrate, the researchers can perform measurements on these tiny areas of freestanding material.
They placed each substrate on a thermal stage to precisely control the temperature, heated each sample and performed micro-Raman spectroscopy. “By performing Raman measurements on the three samples, we can extract something called the temperature coefficient that is substrate dependent,” Zhong explains. “Using these three different substrates, and knowing the TECs of the fused silica and the copper, we can extract the intrinsic TEC of the 2D material.”
They performed this analysis on several 2D materials and found that they all matched theoretical calculations. But the researchers saw something they didn’t expect: the 2D materials fell into a hierarchy based on the elements that comprised them. For instance, a 2D material that contains molybdenum always has a greater TEC than one that contains tungsten.
The researchers dug deeper and learned that this hierarchy is caused by a fundamental atomic property known as electronegativity, which describes the tendency for atoms to pull or extract electrons when they bond. It is listed on the periodic table for each element.
They found that the larger the difference between the electronegativities of the elements that form a 2D material, the lower the material’s thermal expansion coefficient will be. An engineer could use this method to quickly estimate the TEC for any 2D material, rather than relying on complex calculations that typically must be crunched by a supercomputer, says Zhong.
“An engineer can just search the periodic table, get the electronegativities of the corresponding materials, plug them into our correlation equation and within a minute they can have a reasonably good estimation of the TEC,” Zhang says. “This is very promising for rapid materials selection for engineering applications.”
Moving forward, the researchers want to apply their methodology to many more 2D materials, perhaps building a database of TECs. They also want to use micro-Raman spectroscopy to measure the TECs of heterogenous materials, which combine multiple 2D materials. And they hope to learn the underlying reasons for why thermal expansion of 2D materials is different from that of bulk materials.
This story is adapted from material from MIT, with editorial changes made by Materials Today. The views expressed in this article do not necessarily represent those of Elsevier. Link to original source.