This illustration shows the novel optical detection system developed by researchers at Rice University, which heats nanoscale gold wires with a single laser. Image: Natelson Research Group/Rice University.
This illustration shows the novel optical detection system developed by researchers at Rice University, which heats nanoscale gold wires with a single laser. Image: Natelson Research Group/Rice University.

Using a novel optical detection system, researchers at Rice University have found that the electricity generated by temperature differences in nanoscale gold wires doesn't appear to be affected measurably by grain boundaries placed in its way. Grain boundaries are the planes in materials where misaligned crystals meet, forcing atoms along the edge to adjust as they bind to their neighbors.

But the researchers also found that strain and other defects in the gold wires can affect this 'thermoelectric' response. This discovery could allow for the detection of crystalline defects in conducting materials that are difficult to spot and characterize with even the most advanced microscopic methods.

The result was a surprise to researchers led by Rice physicist Doug Natelson and doctoral alumna Charlotte Evans, now a staff scientist at Sandia National Laboratories, who pursued the explanation after seeing measurements they couldn't explain a few years ago.

"A lot of times, people think about the thermoelectric effect when they're building solar panels or generating power from this or that," Evans said. "We argue instead that the thermoelectric effect is a really interesting diagnostic tool." The researchers report their findings in a paper in the Proceedings of the National Academy of Sciences.

The researchers made measurements in bi-crystal gold nanowires produced by the group of Jonathan Fan, an electrical engineer at Stanford University and a co-author of the paper. These measurements showed no detectable effect on thermoelectric voltages at the grain boundary – the electrons in the metal simply ignored the single grain boundary.

Temperature differences in conductors create thermoelectricity through the Seebeck effect. This is one type of thermoelectric effect, and is commonly used to measure temperature differences and to control thermostats. The Natelson lab triggered the Seebeck effect by heating one portion of Fan's wires with a tightly controlled laser, driving electrons to move from the hot location toward colder regions and thus produce a voltage to be measured. No measurable change in this voltage was seen when the laser was moved across the grain boundary in the bi-crystals.

However, when the laser was moved across parts of the same wires that were deformed, with distortions in the crystal lattice throughout the wire, changes in the voltage became apparent. Annealing the distorted devices partly healed the defects, resulting in clear changes in the thermoelectric current.

"There's a community of people who play around with improving thermoelectric response," Natelson said. "They need to be aware that structural issues like very small distortions to the lattice have effects that are not necessarily small. People tend to ignore these tiny structural issues, but anytime you're making thin-film devices, there's baked-in stress and strain in the material, just because of the way it's made."

According to Evans, nanoscale crystals are often characterized using electron backscatter diffraction (EBSD), an expensive and time-consuming process. "The benefit of our process is its simplicity," she said. "We use a large spot size from a laser, two microns, which is much larger than the size of an e-beam, and we can detect variations using just a lock-in technique, a scanning laser and a voltage amplifier.

"If you look at the plain EBSD data, it looks as though you have a pristine crystal. And it's not until you post-process the data and look at how each pixel varies from the next that you would see small distortions along the length of the wire. It's complicated to detect. That's why it's so remarkable that we could detect these little variations with a laser."

"So if you want to do something clever and exploit the thermoelectric response, you need to understand the devices you're making with standard, top-down fabrication methods," Natelson added. "The stress and strain and what seemed like minor structural imperfections can have an easily detectable influence."

This story is adapted from material from Rice University, with editorial changes made by Materials Today. The views expressed in this article do not necessarily represent those of Elsevier. Link to original source.