A new twist on cuprate superconductors

Superconductors have intrigued physicists for decades. But these materials, which allow the perfect, lossless flow of electrons, usually only exhibit this quantum-mechanical peculiarity at temperatures so low – a few degrees above absolute zero – as to render them impractical.

Now, a research team led by Philip Kim, professor of physics and applied physics at Harvard University, has demonstrated a new strategy for making and manipulating a widely studied class of higher-temperature superconductors called cuprates. As the team reports in a paper in Science, this clears a path to engineering new, unusual forms of superconductivity in previously unattainable materials.

Using a unique low-temperature fabrication method, Kim and his team were able to produce a promising candidate for the world’s first high-temperature superconducting diode – essentially, a switch that makes current flow in one direction – made out of thin cuprate crystals. Such a device could theoretically fuel fledging industries like quantum computing, which rely on fleeting mechanical phenomena that are difficult to sustain.

“High-temperature superconducting diodes are, in fact, possible, without application of magnetic fields, and open new doors of inquiry toward exotic materials study,” Kim said.

Cuprates are copper oxides that, decades ago, upended the physics world when researchers discovered they become superconducting at much higher temperatures than theorists had thought possible, although ‘higher’ is a relative term (the current record for a cuprate superconductor is -225°F). But handling these materials without destroying their superconducting phases is extremely complex due to their intricate electronic and structural features.

The team’s experiments were led by Frank Zhao, a former student in the Griffin Graduate School of Arts and Sciences at Harvard University and now a postdoctoral researcher at Massachusetts Institute of Technology (MIT). Using an air-free, cryogenic crystal manipulation method in ultrapure argon, Zhao engineered a clean interface between two extremely thin layers of the cuprate bismuth strontium calcium copper oxide, nicknamed BSCCO (‘bisco’).

BSCCO is considered a ‘high-temperature’ superconductor because it starts superconducting at about -288°F – very cold by practical standards, but astonishingly high among superconductors, which typically must be cooled to about -400°F.

Zhao first split the BSCCO into two layers, each one-thousandth the width of a human hair. Then, at a temperature of -130°F, he stacked the two layers with a 45° twist, like an ice cream sandwich with askew wafers, and showed that the layers retained superconductivity at the fragile interface between them.

The team discovered that the maximum supercurrent that can pass without resistance through the interface is different depending on the current’s direction. Crucially, the team also demonstrated electronic control over the interfacial quantum state by reversing this polarity. This control was what effectively allowed them to make a switchable, high-temperature superconducting diode – a demonstration of foundational physics that could one day be incorporated into a piece of computing technology such as a quantum bit.

“This is a starting point in investigating topological phases, featuring quantum states protected from imperfections,” Zhao said.

This story is adapted from material from Harvard University, with editorial changes made by Materials Today. The views expressed in this article do not necessarily represent those of Elsevier. Link to original source.