This illustration shows how the normal state of a superconducting cuprate abruptly changes when the density of free-flowing electrons is tweaked in a process known as doping. Particle-like excitations that are characteristic of a conventional metal (right) disappear as the 'strange metallic' state (left) takes over. Image: Greg Stewart/SLAC National Accelerator Laboratory.High-temperature superconductors conduct electricity with no loss at much higher temperatures than scientists once thought possible. To figure out how they work, researchers need to understand their ‘normal’ state, from which superconductivity arises when the material is cooled below a critical transition temperature and the density of its free-flowing electrons is tweaked in a process known as ‘doping’.
Even in their normal state, these materials are pretty peculiar. Now, an experiment at the US Department of Energy's SLAC National Accelerator Laboratory by researchers at SLAC and Stanford University has probed the normal state more accurately than ever before. This has revealed an abrupt shift in the behavior of electrons whereby they suddenly give up their individuality and behave like an electron soup. The researchers report their findings in a paper in Science.
"The abnormality of this normal state is suspected to be the reason why these superconductors are such good superconductors," says Dirk Van Der Marel, a researcher at the University of Geneva, Switzerland, who was not involved in the study.
"This study has essentially overthrown a very popular and hotly debated theory, called quantum critical point theory, that is thought to underlie superconductivity, not only in this material but in other materials as well. This is a disruptive finding, but it's a step forward, because it frees our minds to explore other ideas."
The study was carried out on a compound called Bi2212, one of the most thoroughly studied high-temperature superconductors. As a copper oxide, or cuprate, it's one of the family of compounds where high-temperature superconductivity was first discovered more than 30 years ago. Scientists across the world have been working ever since to understand how these materials function, with the goal of finding superconductors that operate at close to room temperature for applications like perfectly efficient power lines.
One of the most important tools for studying these materials is angle-resolved photoemission spectroscopy (ARPES). The technique uses light – in this case, a beam of ultraviolet light from SLAC's Stanford Synchrotron Radiation Lightsource (SSRL) – to kick electrons out of the material and measure their energy and momentum. This reveals how the electrons inside the material behave, which in turn determines its properties. In superconductivity, for instance, electrons overcome their mutual repulsion and form a sort of collective soup in which they can pair up and flow past obstacles without losing any of their energy.
Earlier generations of superconductors, which operate only at extremely low temperatures, are conventional metals in their normal state, where their electrons act independently, as they do in most materials. But in cuprates the picture is very different. Even in their normal, non-superconducting state, electrons seem to recognize each other and act collectively, as if they were dragging each other around, in what's termed ‘strange metal’ and even ‘incoherent strange metal’ behavior.
"In a way you can think about these electrons as being frustrated," said Zhi-Xun Shen, a professor at Stanford and investigator with the Stanford Institute for Materials and Energy Sciences (SIMES) at SLAC who led the study. "In other words, the electrons have sort of lost their individual identity and become part of the soup. This is a really interesting, challenging state to describe in theoretical ways."
According to Su-Di Chen, a Stanford graduate student who helped to perform the experiments, exploring these fascinating normal states at the warm temperatures where they occur has proved difficult.
In ARPES experiments, samples are usually placed in a cold environment inside a vacuum chamber to minimize contamination of the surface. "But even if you put them in an ultra-high vacuum, residual gas molecules can still attach to the sample surface and affect the quality of our measurement," explained Chen. "This problem gets worse when you warm the environment around the sample to the temperatures where the normal states exist."
To get around this, the team found a way to warm the Bi2212 sample, which is about the size of the tip of a ballpoint pen, by heating just the part of the setup that holds it, while keeping everything else cold. This allowed them to examine the electrons' behavior across a range of temperatures and doping levels.
"What we saw was that as you increase the level of doping, there's a very sharp boundary," Hashimoto said. "On one side the electrons are jammed, or frustrated. Then, as more electrons are added, they suddenly start moving smoothly, an indication that the material is now a conventional metal. This transition was known to happen, but the fact that it was so sharp was a real surprise."
These results pose a challenge for theorists who still struggle to explain how high-temperature superconductors work, said paper co-author Jan Zaanen, a theoretical physicist at the University of Leiden in The Netherlands. Current theory predicts that because changes in the nature of Bi2212 are gradual at very low, superconducting temperatures, they should also be gradual at the higher temperatures where the material is in a normal state. Instead the high-temperature changes are abrupt, like when a pot of water starts to boil: you can see either water or bubbles of steam in the roiling pot, but nothing in between.
"There are quite a number of reasons to believe that the strange metal in the normal state may be an example of densely entangled matter," Zaanen said. "Entanglement is the property of the quantum world that sharply distinguishes it from anything classical. We have no theoretical machines, be it classical computers or the available mathematics, that can describe it!
"But quantum computers are designed to handle such densely entangled stuff," he added. "My dream is that these results will eventually land on the top of the list of benchmark problems for the quantum computing community to solve."
This story is adapted from material from the SLAC National Accelerator Laboratory, with editorial changes made by Materials Today. The views expressed in this article do not necessarily represent those of Elsevier. Link to original source.