Hybrid electric energy

Researchers have developed a self-charging power cell that directly converts mechanical energy to chemical energy, storing the power until it is released as electrical current. By eliminating the need to convert mechanical energy to electrical energy for charging a battery, the new hybrid generator-storage cell utilizes mechanical energy more efficiently than systems using separate generators and batteries.

At the heart of the self-charging power cell is a piezoelectric membrane that drives lithium ions from one side of the cell to the other when the membrane is deformed by mechanical stress. The lithium ions driven through the polarized membrane by the piezoelectric potential are directly stored as chemical energy using an electrochemical process.

By harnessing a compressive force, such as a shoe heel hitting the pavement from a person walking, the power cell generates enough current to power a small calculator. A hybrid power cell the size of a conventional coin battery can power small electronic devices – and could have military applications for soldiers who might one day recharge battery-powered equipment as they walked.

The power cell consists of a cathode made from lithium-cobalt oxide (LiCoO₂) and an anode consisting of titanium dioxide (TiO₂) nanotubes grown atop a titanium film. The two electrodes are separated by a membrane made from poly(vinylidene fluoride) (PVDF) film, which generates a piezoelectric charge when placed under strain. When the power cell is mechanically compressed, the PVDF film generates a piezoelectric potential that serves as a charge pump to drive the lithium ions from the cathode side to the anode side. The energy is then stored in the anode as lithium-titanium oxide.

Charging occurs in cycles with the compression of the power cell creating a piezopotential that drives the migration of lithium ions until a point at which the chemical equilibrium of the two electrodes are re-established and the distribution of lithium ions can balance the piezoelectric fields in the PVDF film. When the force applied to the power cell is released, the piezoelectric field in the PVDF disappears, and the lithium ions are kept at the anode through a chemical process.

The charging cycle is completed through an electrochemical process that oxidizes a small amount of lithium-cobalt oxide at the cathode to Li1-xCoO₂ and reduces a small amount of titanium dioxide to LixTiO₂ at the anode. Compressing the power cell again repeats the cycle.

When an electrical load is connected between the anode and cathode, electrons flow to the load, and the lithium ions within the cell flow back from the anode side to the cathode side.

Using a mechanical compressive force with a frequency of 2.3 Hertz, the researchers increased the voltage in the power cell from 327 to 395 millivolts in just four minutes. The device was then discharged back to its original voltage with a current of one milliamp for about two minutes. The researchers estimated the stored electric capacity of the power cell to be approximately 0.036 milliamp-hours.

Beyond the efficiencies that come from directly converting mechanical energy to chemical energy, the power cell could also reduce weight and space required by separate generators and batteries. The mechanical energy could come from walking, the tires of a vehicle hitting the pavement, or by harnessing ocean waves or mechanical vibrations.

This story is reprinted from material from Georgia Tech, with editorial changes made by Materials Today. The views expressed in this article do not necessarily represent those of Elsevier. Link to original source.