“The paper provides a unified theory to why this electrolyte works better and the key understanding of it came by finding that micelle-like structures form within this electrolyte – like they do with soap.”Bin Li, Oak Ridge National Laboratory
When it comes to making batteries that last longer, a team including researchers at Brown University and Idaho National Laboratory believes the key might be in the way soap gets things clean.
Take handwashing. When someone washes their hands with soap, the soap forms structures called micelles that trap and remove grease, dirt and germs when flushed with water. The soap does this because it acts as bridge between the water and what is being cleaned away, by binding them and wrapping them into those micelle structures.
The team of researchers noticed that a similar process plays out in what has become one of the most promising substances for designing longer-lasting lithium-metal batteries — a new type of electrolyte called a localized high-concentration electrolyte. As the researchers report in a paper in Nature Materials, their new understanding of how this process works might be the missing piece to fully kicking the door open on this emerging battery technology.
“The big picture is that we want to improve and increase the energy density for batteries, meaning how much energy they store per cycle and how many cycles the battery lasts,” said Yue Qi, a professor in Brown’s School of Engineering. “To do this, materials inside of traditional batteries need to be replaced to make long-life batteries that store more energy a reality – think batteries that can power a phone for a week or more, or electric vehicles that go for 500 miles.”
Scientists have been actively working to transition to batteries made from lithium metal because they have a much higher energy-storage capacity than today’s lithium-ion batteries. The holdup is the electrolyte, which allows an electrical charge to pass between a battery’s two terminals, sparking the electrochemical reaction needed to convert stored chemical energy to electrical energy. The traditional electrolytes used in lithium-ion batteries, which essentially comprise a low-concentration salt dissolved in a liquid solvent, don’t do this effectively in metal-based batteries.
Localized high-concentration electrolytes were engineered by scientists at Idaho National Laboratory and Pacific Northwest National Laboratory to address this challenge. They are made by mixing high concentrations of salt in a solvent with another liquid called a diluent, which makes the electrolyte flow better so that the power of the battery can be maintained.
So far, in lab tests, this new type of electrolyte has shown promising results, but how and why it works has never been fully understood – putting a cap on how effective it can be and how it can be better developed. This is what the new study helps to address.
“The paper provides a unified theory to why this electrolyte works better and the key understanding of it came by finding that micelle-like structures form within this electrolyte – like they do with soap,” said Bin Li, a senior scientist at Oak Ridge National Laboratory who worked on the study. “Here we see that the role of the soap or surfactant is played by the solvent that binds both the diluent and the salt, wrapping itself around the higher concentration salt in the center of the micelle.”
By understanding this, the researchers were able to break down the ratios and concentrations needed to bring about the optimal reactions for the batteries. This should help solve one of the main sticking points in engineering this electrolyte: finding the proper balance for the three ingredients. In fact, this study not only provides better guidelines for making localized high-concentration electrolytes that function, but also for making ones that work even more effectively.
Researchers at Idaho National Laboratory have already set about putting this theory into practice, finding that, so far, it holds up and helps to extend the life of lithium-metal batteries. The team is excited to see what designs for localized high-concentration electrolytes come from their work but know that significant progress is required to overcome the electrolyte-design bottleneck for high-density batteries. Right now, they are amused that the secret may have been in something as mundane and everyday as soap.
“The concept of the micelle may be new for the electrolyte, but it’s actually very common for our daily life,” Qi said. “Now we have a theory, and we have guidelines to get interactions we want from the salt, the solvent and the diluent in the electrolyte, and what concentration they have to be at and how you mix them.”
This story is adapted from material from Brown University, with editorial changes made by Materials Today. The views expressed in this article do not necessarily represent those of Elsevier. Link to original source.